Attachment of PbS quantumdots (QD) to single-walled carbon nanotubes (SWNT) andmultiwalled carbon nanotubes(MWCNT)\nis described; wherein commercially obtained PbS-QD of size 2.7 nm, stabilized by oleic acid, are added to a suspension of singleormultiwalled\ncarbon nanotubes (CNT) prefunctionalized noncovalently with 1,2-benzenedimethanethiol (1,2-BDMT) in ethanol.\nThe aromatic part of 1,2-BDMTattaches to the CNT by ??-?? stacking interactions, noncovalently functionalizing the CNT.The thiol\npart of the 1,2-BDMTon the functionalizedCNTreplaces oleic acid on the surface of theQDfacilitating the noncovalent attachment\nof the QD to the CNT.The composites were characterized by TEM and FTIR spectroscopy. Quenching of NIR fluorescence of the\nPbS-QD on attachment to the carbon nanotubes (CNT) was observed, indicating FRET from the QD to the CNT.
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